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Study on Preparation and Corrosion Resistance of Graphene-Ni35Co30Cu20Fe15 High Entropy Alloy Composites

Received: 10 May 2017     Published: 11 May 2017
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Abstract

The graphene/Ni35Co30Cu20Fe15 high entropy alloy composites were successfully prepared by ball milling and spark plasma sintering (SPS) methods. The microstructures and structures of graphene and composites were measured by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and Raman spectroscopy. The hardness and corrosion resistance of the composites were tested by Vivtorinox hardness tester and chemical workstation. The results showed that the homogeneous distribution of graphene in the composites can be achieved by ball milling, and the original structure of graphene was not destroyed. The addition of graphene improved the hardness and corrosion resistance of high entropy alloy composites. Compared with the Ni35Co30Cu20Fe15 high entropy alloy, the hardness of the high entropy alloy with 0.3 wt.% Graphene increased from 255HV to 310HV. The addition of graphene increased the corrosion potential of the composite in 3.5% NaCl solution from -0.5V to -0.2V and the corrosion current density from 2×10-5A/cm2 reduced to 8×10-6A/cm2, which greatly improved the corrosion resistance of the material.

Published in Science Discovery (Volume 5, Issue 3)
DOI 10.11648/j.sd.20170503.12
Page(s) 169-173
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Graphene, Composite Materials, Corrosion Resistance

References
[1] Geim A. K, Novoselov K. S. The rise of graphene [J]. Nature Materials, 2007, 6(3): 183-191.
[2] 张芸秋,梁勇明,周建新等.石墨烯掺杂的研究进展[J].化学学报,2014,72(3):367-377。
[3] 邢玉雷,徐克,蔡光兰等.单层石墨烯制备及其耐腐蚀特性实验研究[J].现代化工,2016,36(03):87-90。
[4] 邢玉雷,徐克,蔡光兰等.单层石墨烯制备及其耐腐蚀特性实验研究[J].现代化工,2016,36(03):87-90。
[5] Chae H. K, Siberio-Pérez D. Y, Kim J,et al.. A route to high surface area, porosity and inclusion of large molecules in crystals[J]. Nature, 2004, 427(5): 523-527.
[6] Zhang Y, Tan Y. W, Stormer H. L, et al. Experimental observation of the quantum Hall effect and Berry’s phase in graphene[J]. Nature, 2005, 438(7065): 201-204.
[7] 王宏智,高翠侠,张鹏等.石墨烯/聚苯胺复合材料的制备及其电化学性能[J].物理化学学报,2013,29(1):117-122。
[8] 杨文彬,张丽,刘菁伟等.石墨烯复合材料的制备及应用研究进展[J].材料工程,2015,3(43):91-97。
[9] 燕绍九,杨程,洪起虎等.石墨烯增强铝基纳米复合材料的研究[J].材料工程,2014,(04):1-6。
[10] Jing-fu LI, Lei ZHANG, Jin-kun XIAO,et al.. Sliding wear behavior of copper-based composites reinforced with graphene nano -sheets and graphite[J]. Transactions of Nonferrous Metals Society of China, 2015, (10): 3354-3362.
[11] Yeh J. W, CHEN S. K, LIN S. J, et al.. Nano -structured high entropy alloys with multiple principal elements:novel alloy design concepts and outcomes[J]. Advanced Engineering Materials, 2004, 6(5): 299-303.
[12] 付志强.AlCrFeNi-M系高熵合金及其复合材料组织与性能研究[D].黑龙江:哈尔滨工业大学,2011:1-85。
[13] 黄宛真,杨倩,叶晓丹等.石墨烯层数的表征[J].材料导报,2012,(07):26-30。
[14] TUINSTRA F, KOENIG K. L. Raman spectrum of graphite[J]. The Journal of Chemical Physics, 1970, 53 (3): 1126-1130.
[15] 吴娟霞,徐华,张锦等.拉曼光谱在石墨烯结构表征中的应用[J].化学学报,2014,72(3):301-318。
[16] 彭黎琼,谢金花,郭超,张东.石墨烯的表征方法[J].功能材料,2013,(21):3055-3059。
[17] 邱星武,张云鹏,刘春阁.激光熔覆法制备Al2CrFeCoxCuNiTi高熵合金涂层的组织与性能[J].粉末冶金材料科学与工程,2013,18(5):735-740。
[18] Kuang D, Xu L, Liu L, et.al.. Graphene-nickel composites[J]. Applied Surface Science, 2013, 273(6): 484-490.
[19] Tang Y, Yang X, Wang R, et.al. Enhancement of the mechanial properties of graphanen-copper composites with graphene-nickel hybrids[J]. Materials Science and Engineering: A, 2014, 599(2): 247-254.
[20] Chu K, Jia C. Enhanced strength in bulk graphene-copper composites[J]. Physic Status Solidi, 2014, 211(1): 184-190.
[21] 胡树兵,蓝花,陈燕玉.电刷镀n-SiC/Ni-W-Co复合镀层的组织结构和电化学腐蚀行为[J].材料保护,2014,47(1):9-12。
[22] 叶晓慧.激光快速原位制备石墨烯及其耐腐蚀性研究[D].北京:清华大学,2015:1-134。
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  • APA Style

    Lingyu Xu, Hongnian Cai, Xingwang Cheng, Pei Wang, Meng Wang. (2017). Study on Preparation and Corrosion Resistance of Graphene-Ni35Co30Cu20Fe15 High Entropy Alloy Composites. Science Discovery, 5(3), 169-173. https://doi.org/10.11648/j.sd.20170503.12

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    ACS Style

    Lingyu Xu; Hongnian Cai; Xingwang Cheng; Pei Wang; Meng Wang. Study on Preparation and Corrosion Resistance of Graphene-Ni35Co30Cu20Fe15 High Entropy Alloy Composites. Sci. Discov. 2017, 5(3), 169-173. doi: 10.11648/j.sd.20170503.12

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    AMA Style

    Lingyu Xu, Hongnian Cai, Xingwang Cheng, Pei Wang, Meng Wang. Study on Preparation and Corrosion Resistance of Graphene-Ni35Co30Cu20Fe15 High Entropy Alloy Composites. Sci Discov. 2017;5(3):169-173. doi: 10.11648/j.sd.20170503.12

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  • @article{10.11648/j.sd.20170503.12,
      author = {Lingyu Xu and Hongnian Cai and Xingwang Cheng and Pei Wang and Meng Wang},
      title = {Study on Preparation and Corrosion Resistance of Graphene-Ni35Co30Cu20Fe15 High Entropy Alloy Composites},
      journal = {Science Discovery},
      volume = {5},
      number = {3},
      pages = {169-173},
      doi = {10.11648/j.sd.20170503.12},
      url = {https://doi.org/10.11648/j.sd.20170503.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20170503.12},
      abstract = {The graphene/Ni35Co30Cu20Fe15 high entropy alloy composites were successfully prepared by ball milling and spark plasma sintering (SPS) methods. The microstructures and structures of graphene and composites were measured by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and Raman spectroscopy. The hardness and corrosion resistance of the composites were tested by Vivtorinox hardness tester and chemical workstation. The results showed that the homogeneous distribution of graphene in the composites can be achieved by ball milling, and the original structure of graphene was not destroyed. The addition of graphene improved the hardness and corrosion resistance of high entropy alloy composites. Compared with the Ni35Co30Cu20Fe15 high entropy alloy, the hardness of the high entropy alloy with 0.3 wt.% Graphene increased from 255HV to 310HV. The addition of graphene increased the corrosion potential of the composite in 3.5% NaCl solution from -0.5V to -0.2V and the corrosion current density from 2×10-5A/cm2 reduced to 8×10-6A/cm2, which greatly improved the corrosion resistance of the material.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Study on Preparation and Corrosion Resistance of Graphene-Ni35Co30Cu20Fe15 High Entropy Alloy Composites
    AU  - Lingyu Xu
    AU  - Hongnian Cai
    AU  - Xingwang Cheng
    AU  - Pei Wang
    AU  - Meng Wang
    Y1  - 2017/05/11
    PY  - 2017
    N1  - https://doi.org/10.11648/j.sd.20170503.12
    DO  - 10.11648/j.sd.20170503.12
    T2  - Science Discovery
    JF  - Science Discovery
    JO  - Science Discovery
    SP  - 169
    EP  - 173
    PB  - Science Publishing Group
    SN  - 2331-0650
    UR  - https://doi.org/10.11648/j.sd.20170503.12
    AB  - The graphene/Ni35Co30Cu20Fe15 high entropy alloy composites were successfully prepared by ball milling and spark plasma sintering (SPS) methods. The microstructures and structures of graphene and composites were measured by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and Raman spectroscopy. The hardness and corrosion resistance of the composites were tested by Vivtorinox hardness tester and chemical workstation. The results showed that the homogeneous distribution of graphene in the composites can be achieved by ball milling, and the original structure of graphene was not destroyed. The addition of graphene improved the hardness and corrosion resistance of high entropy alloy composites. Compared with the Ni35Co30Cu20Fe15 high entropy alloy, the hardness of the high entropy alloy with 0.3 wt.% Graphene increased from 255HV to 310HV. The addition of graphene increased the corrosion potential of the composite in 3.5% NaCl solution from -0.5V to -0.2V and the corrosion current density from 2×10-5A/cm2 reduced to 8×10-6A/cm2, which greatly improved the corrosion resistance of the material.
    VL  - 5
    IS  - 3
    ER  - 

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Author Information
  • School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, China

  • School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, China

  • School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, China

  • School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, China

  • School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, China

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